Advances in molten slags, fluxes, and salts: proceedings of by Ramana G. Reddy, Pinakin Chaubal, P. Chris Pistorius, Uday

By Ramana G. Reddy, Pinakin Chaubal, P. Chris Pistorius, Uday Pal

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L. S. Darken, "Thermodynamics of Binary Metallic Solutions", Transactions of the Metallurgical Society of AIME, 239(1967) 80-89 28 Advances in Molten Slags, Fluxes, and Salts: Proceedings of The 10th International Conference on Molten Slags, Fluxes and Salts (MOLTEN16) Edited by: Ramana G. Reddy, Pinakin Chaubal, P. Chris Pistorius, and Uday Pal TMS (The Minerals, Metals & Materials Society), 2016 REFRACTORY METALS RECOVERY FROM INDUSTRIAL WASTES Trail Vin LONG1, Hronori MURASE2, Takahiro MKI 3 , Yasushi SASAKI4 and Mtsutaka HINO5 'Graduate student, Tohoku University; nowMOIT; Vietnam Graduate student, Tohoku University; nowAichi Steel Co.

Together with dicacliumsilicate equilibrated liquids, the relationship between theoretical liquidus temperatures and critical temperatures is expressed in Fig. 7. 0 software. A1 2 0 3 + 2 CaO + Si0 2 = Ca 2 Al 2 Si0 7 (6) a n AG = - 5 0 3 0 5 . 33T [J/mol , K c = Ca2Al2Si07 2 a-cao a-Al2o3 asio2 i C a O + i A l 2 0 3 + Si0 2 = i C a A l 2 S i 2 0 8 AG = - 4 7 9 9 7 . 34T [J/mol], K M S 2 = 1 2 22 "-CaO (8) . Z T ^ k a ' X"-Al203 ' (7) X1si02 ^ 1800 "T" • 1750 "T" Han and Min (under progress) AI2Os-CaO-'FeO'-SiO!

The effect of MgO content on viscosity and structure of the typical blast furnace slags is described in Fig. 2. As MgO content increases, viscosity of the slag gradually decreases until the curve reaches the local minima, generally at MgO content of 7 to 11 %, depending on the basicity and A1 2 0 3 contents. Viscosity increases with increasing MgO content after the minima. The minima in viscosity coincide with the primary solidification phase transition composition from melilite to spinel. From FT-IR spectra, the structural relaxation is maximized at 7 % addition of MgO as well.

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