Advances in Inorganic Phosphate Materials: Ceramic by Ilias Belharouak, Vilas G. Pol

By Ilias Belharouak, Vilas G. Pol

This book offers a great one-stop source for knowing crucial present concerns within the examine and advances in inorganic phosphate materials.Content:

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F) A. Cabeza, M. A. G. Aranda, S. Bruque, D. M. Poojary, A. Clearfield and J. Sanz, Aluminum Phenylphosphonates: A Fertile Family of Compounds, Inorg. , 37, 4168-78 (1998). (j) J· Rocha, Z. Lin, C. Fernandez, and J-P. Amoureux, Multiple-quantum 27A1 MAS NMR spectroscopy of microporous aluminium methylphosphonate AIMepO-ß, Chem. , 22 , 2513-14 (1996). (h) G. B. Hix, V. J. Carter, D. S. Wragg, R. E. Morris, and P. A. Wright, The synthesis and modification of aluminium phosphonates, J. Mater. , 9, 179-185 (1999).

The best transformation ratio of 15% was resulted under dry 28 · Advances in Inorganic Phosphate Materials Preparation of P-N Compounds and Their Application to Fireproofing Substance ammonia and APP sample melted under humid air even at the lowest temperature of 250 °C. Anyway, complete phase transition of APP from form I to II was not obtained under the simple atmospheric condition. Accordingly, the phase transition under alternating gas flow of dry Table 1. Preferable phase-transition condition of APP form I to II Alternating Total reaction flow gas/min time/min Wet NH3 Con.

Advances in Inorganic Phosphate Materials · 33 Preparation of P-N Compounds and Their Application to Fireproofing Substance 1. Preparation of melamine diphosphate Melamine diphosphate (MDP) is usually prepared by heating melamine orthophosphate at about 200 °C, but the preparation of pure melamine orthophosphate is not easy and it is difficult to keep high quahty of the product of the diphosphate, especially for factory scale production. Direct preparation of melamine diphosphate from reaction system of melamine-ammonium orthophosphate was examined at heating temperature of 190-260 °C with several kinds of mixing ratio of melamine and ammonium orthophosphate in this experiment.

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