A textbook of inorganic chemistry vol.VII part I Oxigen

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Dilute solution theory with no interactions is assumed. 8 ____ .... 067- The estimated conductivities are slightly higher than the actually measured values. 05 S/cm. The reason for the discrepancy is interaction (incomplete dissociation) of the ionic species that are assumed here to be completely dissociated. Nonetheless, the trends illustrated are valid. As noted from Table 2, the major contribution (91%) to the conductivity is derived from the acid, and in particular (80%) from the proton due to its high mobility.

Since the limiting current depends on the concentration and on the agitation rate, high reactant concentration and sufficient transport will promote smooth deposition. Electrochemical Society Proceedings Volume 99-9 29 Controlling the Current Distribution on the Macroscopic and Microscopic Scales Since the current distribution on the macroscopic and microscopic scales is dominated by different mechanisms, different means must be applied to control it. On - the wafer (macro-) scale: Uniformity can be provided through hardware design, cell shape, shields, etc.

B. W. Gregory, Langmuir, 4, 1368 (1988). 12. K. Motai, T. Hashizume, H. Lu, D. Jeon, T. Sakurai and H. Pickering, Appl. Surf. , 67, 246 (1993) 13. J. M. Lambert, Surf. , 67, 180 (1977). 14. G. Jones and M. Kadodwala, Surf. , 370, L219 (1997). 15. K. Bange, R. E. K. Sass, Vacuum, 33, 757 (1983). 16. W. J. Bard, J. Amer. Chem. , 116, 10725 (1994). 17. W. J. Bard, J. Phys. , 99, 8351 (1995). 18. P. Moffat, in Nanostructured Materials in Electrochemistry, eds. P. Searson and J. Meyer, PV 95-8, p. , Pennington, NJ (1995).

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